-关于农残检测中的基质效应的原理

这两篇文献还是很不错的；我们做有机磷农药残留的时候经常会遇到基质效应。

那篇比较老了，这是介绍基质效应研究过程和现状比较全面的Matrix-induced response enhancement in pesticideresidue analysis by gas chromatography1The sample matrix can cause an enhancement in the observed chromatographic response for pesticide residues in a matrix extract compared with the same concentration in a matrix-free solution. The matrix increases the transfer of pesticides from hot vaporizing injectors by reducing the thermal stress for labile compounds and by masking active sites in the injector responsible for the adsorption or decomposition of polar pesticides.The use of different injector types and matrix simplification procedures can reduce matrix-induced enhancement but do not eliminate it. The most effective strategy is to use matrix-matched calibration standards or analyte protectants which equalize the response enhancement for calibration standards and sample extracts. From a practical point of view it is important that the method used to correct for matrix-induced enhancement is compatible with low system maintenance. The different approaches for correcting matrix-induced enhancement for calibration in pesticide residue analysis are discussed and compared in this review.

现在很多国家标准都没有考虑基质效应，不知道制定标准 的专家是如何想的