请教有关内标物的类型
首页 > 问题列表 > 详情

请教有关内标物的类型

请教分析中内部质量控制使用的内标物是不是有所谓的程序性内标物(procedural internal standards)和仪器内标物(instrument internal standards) 不知道具体是不是这么叫的,还望高人赐教! 展开全部∨ 2 回答 ·  2 关注
共2个回答
另外,我对上段中提到的the mean recovery +/- 2x %RSD 及beyond +/-20 %RSD也感到很模糊,是不是什么地方印错了,是正负20 %的RSD?
  1 0
补充:上述两个词是我在翻译欧盟最新农残质量控制程序中遇到的,为方便讨论,我将整段摘录如下,另附其英文版全文:Acceptable limits for a individual recovery result should normally be in the range of the mean recovery +/- 2x %RSD and may be adjusted using repeatability (validation) and intra-laboratory reproducibility (routine on-going recovery) data. Recoveries outside this range usually require re-analysis of the batch but may be acceptable in certain justified cases. Where the individual recovery is unacceptably high and no residues are detected, it is not necessary to re-analyse the samples to prove the absence of residues. However, consistently high recovery should be investigated. If a significant trend occurs in recovery, or potentially unacceptable (beyond +/-20 %RSD) results are obtained, the cause(s) must be investigated. In order to assure the correct execution of the whole procedure for each individual sample and the correct injection of each final sample extract in the GC- or LC-system, the use of one or? more quality control (QC-) internal standards, so-called procedurale? and instrument? internal standards, is recommended. These compounds, which are added to the samples prior to extraction and to the final sample extract just before injection, should be chosen to be outside of the target pesticide scope and should preferably represent the entire spectrum of pesticides in terms of polarity and susceptibility to degradation. The recovery of these QC-standards should be within the limits specified by the laboratory but at least within the abovementioned range for individual recovery. 欧盟农残质量控制程序
  9 0
相关问题
固相微萃取-气相色谱法快速检测库尔勒香梨中有机磷农药残留量 24个回答
关于顶空固相微萃取 气相色谱质谱(SPME GC-MS)的一些问题 8个回答
固相微萃取-气相色谱-质谱联用技术检测 蔬菜、水果中15种有机氯农药残留量 20个回答
固相微萃取-气相色谱联用检测茶叶中的农药残留 7个回答
注射式萃取净化法-质谱检测蔬菜中农药残留 28个回答
编辑推荐
单锥螺带真空干燥机的优点? 1个回答
我国“无麸质”食品有什么管理标准吗? 1个回答
复配酶制剂中的辅料有何规定?配料如何标识? 1个回答
白芸豆提取物的提取方法、测定方法及应用是什么? 1个回答
粮食食用油快速检测解决方案有哪些? 1个回答
 
关注问题 写回答